[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy)-5-[(2,2,2-trifluoroacetyl)amino]phenyl]methylene]-ruthenium - Names and Identifiers
Name | [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy)-5-[(2,2,2-trifluoroacetyl)amino]phenyl]methylene]-ruthenium
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Synonyms | M71-S1Pr Umicore M71 SIPr [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro-[(2-isopropoxy)(5-trifluoroacetamido)benzylidene]ruthenium(II) [1,3-Bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dichloro[(2- isopropoxy)(5-trifluoroacetamido)benzylidene]ruthenium(II) [1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetamido)phenyl]methyleneruthenium(II) [1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroiMidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetaMido)phenyl]MethylenerutheniuM(II) dichloride M71-S1Pr [1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetamido)phenyl]methyleneruthenium(II) dichloride omega CS1 [1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy)-5-[(2,2,2-trifluoroacetyl)amino]phenyl]methylene]-ruthenium
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CAS | 1212008-99-5
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InChI | InChI=1S/C27H38N2.C12H12F3NO2.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-7(2)18-10-5-4-9(6-8(10)3)16-11(17)12(13,14)15;;;/h9-14,18-21H,15-16H2,1-8H3;3-7H,1-2H3,(H,16,17);2*1H;/q;;;;+2/p-2 |
[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy)-5-[(2,2,2-trifluoroacetyl)amino]phenyl]methylene]-ruthenium - Physico-chemical Properties
Molecular Formula | C39H50Cl2F3N3O2Ru
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Molar Mass | 821.8044096 |
Melting Point | >300 °C |
Appearance | Powder |
Color | green |
Storage Condition | Room Temprature |
[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy)-5-[(2,2,2-trifluoroacetyl)amino]phenyl]methylene]-ruthenium - Risk and Safety
[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy)-5-[(2,2,2-trifluoroacetyl)amino]phenyl]methylene]-ruthenium - Introduction
[1,3-Bis [2,6-diisopropylphenyl]-2-imidazolidinylidene] dichloro [[2-(isopropoxy)-5-[(2,2, 2-trifluoroacetyl) amino] phenyl] methylene]-ruthenium (abbreviated as imidazolylruthenium) is a metal-organic complex.
Properties: The chemical formula of imidazolyl ruthenium is [C25H34Cl2F3N5O2Ru], and the appearance is yellow solid. It can present three reversible oxidation states in solution and can realize different electron transfer reactions. Imidazolyl ruthenium has good stability and catalytic activity, and can be used as oxidants, reductants and catalysts.
Application: Imidazolyl ruthenium can be used in the field of organic synthesis, for asymmetric synthesis, reduction reaction, oxidation of aromatic compounds, etc. It also has applications in the field of organic optoelectronics, such as photocatalysis, organic solar cells, etc.
Preparation method: The preparation of imidazolyl ruthenium is more complicated. A common method is to prepare by reacting a series of compounds. The specific steps can be consulted in relevant literature or patents.
Last Update:2024-04-10 22:29:15